Bart, this wasn't really about Movies but audio albums. Although I can see where the advice might be helpful (thanks).
MrC, yes I am aware they are "just letters", but I was inquiring if there was a method I could use to figure them into the sorting pattern, i.e perhaps someone had a custom expression that dealt with this. I have not used Expressions extensively and know little about them, but I hope to learn more when I have some free time.
Ideally, yes I would expect a Date or Year sort to put them in order - but that still does not sort things properly in my library. I still have albums coming up before other albums even though they were released after those albums, and as far as I know my dates are tagged correctly..
Of course there are SO many options within Media Center and so many tags, that I probably am failing to grasp certain idiosyncrasies the program may have in how it uses this data... I don't know (i.e I don't really understand the point of the "Auto" tag fields that build themselves based on other tags' data... I'd rather get rid of / turn off that functionality if possible).
However I think I may have solved my issue, for the time being..
I now use the following sort order
Artist(a-z) > Year (a-z)> Album (a-z)
Although I'm gonna have to modify that into something workable so I can still group series.. Perhaps using Barts suggestion, since my Final Fantasy Tactics OST is way off by itself, due to it not being composed by Nobuo Uematsu, like the other FF albums I have.
I definitely have a lot of work to do in learning how sorting works and how priority is assigned to the various tags you select to sort by and such.. I can already see this spilling over into my Video library which I will be building up and tagging very soon. Lots of related TV Shows / Movies, some coming out the same year but different months, etc.. Gonna have to learn how to efficiently tag and sort all that