Sorry, I am AHCI ignorant. When I turn AHCI on does it turn on for all the other SATA ports at the same time and will this cause any problems with my other 5 HDDs and 2 optical drives?
When you turn on AHCI or RAID mode, it is a setting for the controller (the part on your motherboard, or in the CPU). It applies to all of the ports "from" one controller. You turn this on in the BIOS of your Motherboard (which on your ASUS is one of those fancy new graphical ones).
The default is usually "old-school emulation mode" to allow compatibility with really old operating systems, like Windows 95 and whatnot. They
might have actually changed this and enabled AHCI by default on the new ASUS Z77 boards. I don't remember, but I vaguely remember being happy about something
like this that they changed.
It should NOT impact the optical drives in your system, unless you got a really old crappy one (first SATA drive ever, for example). I'm sure there are exceptions, but my SATA Optical drives all work fine with AHCI or RAID mode enabled.
AHCI vs RAID:These are functionally the same. RAID is a super-set of the AHCI mode. It includes all the AHCI goodness, and enables RAID goodness too. It does change which drivers are installed in Windows, though. Since these drivers are required to access the drive, you can't (easily) switch from one to the other post-install (the drive is kinda needed even during boot).
* If you need to RAID some disks, even if not all of them on a particular controller, enable RAID mode.
* If you don't now need RAID, and don't expect to ever need RAID in the future, then enable AHCI mode (keep it simpler).
* Don't ever leave it set to Legacy/PATA emulation mode (usually the default). Sometimes you need to switch it back to this temporarily in order to do a firmware update on the drive. But you won't be able to boot to Windows that way (it'll bluescreen).
Other Tips:Install the SSD boot volume on one of your two Intel-based 6G SATA ports. Don't use it on one of the Marvel/ASMedia auxiliary ports. They'll be more troublesome, especially with a boot volume (even though the ASMedia eSATA are well behaved, I still trust the Intel ones much more, and they perform better anyway).