MC does not have the ability to do any operations on DSD containers as native DSD. MC can transmit native DSD or DSD as DoP. Both of these techniques just send the DSD data down the line to the DAC and let the DAC do the DSD to analog decoding. If the DAC has a volume control, then that volume control can be used. Obviously a preamp can be used also, which I'm sure you know and you are probably avoiding on purpose to try to get a more "pure" signal path.
If MC is told to do any alterations on DSD, including volume, it can do them, but MC must first convert the DSD to PCM. Then any DSP (including volume) can be applied in the PCM domain. MC can also convert the resulting bits back to DSD if you want. But the "pureness" of the DSD is entirely lost, as it goes DSD > PCM > DSP processing > DSD .
You could turn all of this on by disabling bitstreaming, and then enabling Output Encoding as DSD. Note that this will convert ALL PCM to DSD on output.
I don't think this is terribly useful, but maybe you like the idea and/or want to play around with it.
Brian.