Sure. The best way is basically:
1. On old PC, turn the "fix broken links" option in auto-import OFF, and DISABLE auto import. Then make a library backup.
2. Copy all the audio files to the new pc in their new location
3. Copy the library backup file over to the new PC
4. Do a library restore on the new pc using the library backup file.
5. Use RMCF to fix the paths.
https://wiki.jriver.com/index.php/Rename,_Move,_and_Copy_FilesSpecifically, the option you will want to use is "Update database to point to new location". It's in the dropdown at the top of the dialog.
I would just use the "Find and Replace" functionality (turning off the Directories and Filename options) to replace the old base path with the new base path. The preview on the right will show you what will happen, before you commit.
When you look at MC after step 4, you will see all your files in your views, but they will show as broken links. Then you fix the paths with RMCF, and the links will no longer be broken, if you did it correctly.
Step 1 is very important. Don't use an old library backup if you had auto-import and fix broken links turned on. If you fail to heed this warning, after you restore the library backup, MC will see that the files are missing from where it remembers them, and promptly delete them from your library, which will also destroy all your playlists. There will be tears. You'll have to start over.
Hope this helps...